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Episode 1

HYDROGEN
GENERATION

Green hydrogen is produced from renewable energy by the electrolysis process. This means using an electric current to split water molecules into hydrogen and oxygen. Alkaline electrolysis (AEC) and Proton Exchange Membrane Electrolysis (PEMEC) are among the major technologies for producing green hydrogen.

Renewable energies power up the electrolyser which separates water into hydrogen and oxygen.

WATER

ELECTROLYZER

RENEWABLES

AEC | ALKALINE ELECTROLYSIS

An alkaline electrolyser cell consists of a pair of electrodes separated by a diaphragm filled with an alkaline solution, typically potassium hydroxide (KOH), in a concentration between 25% and 30%. Water is split at the cathode to form H2 while O2 forms at the anode. 

Gas Cooler

Hydrogen

Oxygen

Recooling

Gas Separators

AEC Electrolyzer

Lye Cooler

Water Tank

Potassium Hydroxide Tank

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Gas Cooler

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Water

KOH / Lye

Hydrogen

Oxygen

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FOCAL-POINT: 
COMPARISON OF HEAT EXCHANGERS
IN ELECTROLYSIS

To ensure that the electrolysis occurs in stable and efficient conditions, it is therefore essential that all
plant and equipment interacting with the process, especially the heat exchangers, are carefully chosen and designed. Kelvion Products offers several heat exchanger solutions for thermal management in electrolysis systems. This paper will discuss and compare the different options for electrolyzer process cooling and also present options for auxiliary cooling.

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READ MORE and DOWNLOAD OUR TECH-PAPER

PEMEC | PROTON EXCHANGE MEMBRANE ELECTROLYSIS

Proton exchange membrane electrolysis (PEMEC) uses a solid polymer electrolyte - the proton exchange membrane - around which water flows. When an electrical voltage is applied to the membrane, protons migrate through it: hydrogen is produced at the cathode and oxygen at the anode.

The electrolysers do not contain liquid electrolytes, but a solid, semi-permeable membrane through which the protons migrate.
 

Gas Cooler

Hydrogen

Oxygen

Recooling

Gas Separators

PEMEC Electrolyzer

Cell Cooler

Water Tank

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Gas Cooler

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Water

Hydrogen

Oxygen

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ALKALINE ELECTROLYSIS VERSUS
PROTON EXCHANGE MEMBRANE ELECTROLYSIS

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AEC ADVANTAGES

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⊲ Low cost compared to PEMEC due to 
   regular materials

⊲ High technology readiness levels
   and proven concept
⊲ Long lifetimes of more than 10 years

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PEMEC ADVANTAGES

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⊲ Short response and start up time
⊲ Good part load capability
⊲ Smaller size compared to
   Alkaline Electrolyser
⊲ High current density
⊲ High electrolyser efficiency

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AEC DRAW BACKS

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⊲ Alkaline setup required
⊲ Long start up and response time
⊲ Decreasing performance in part load
⊲ Requires bigger footprint than PEMEC
⊲ Lower electrolyser efficiency compared
   to PEMEC

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PEMEC DRAW BACKS

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⊲ High Cost due to precious metal
   catalyst required
⊲ Comparatively short lifetime
   of 3-4 years

DELIVERING THE FULL SCOPE

Water Supply

Power Supply

Electrolysis

Gas Purification

Gas Compression

Storage and Transportation

We have a long history in the heat exchanger business. In addition to heat exchangers for the core electrolysis system, our portfolio includes solutions for the auxiliary up and downstream processes in power-to-gas applications. We have also successfully supplied heat exchanger solutions for water treatment. Our transformer cooling systems are operating  worldwide. Both applications can be found in the upstream process in electrolyser power-to-gas plants. For downstream applications we can rely on our know how and experience in gas purification and compression applications. We are pleased to consult with and serve you regarding all auxiliary processes in electrolyser plants.

OUR SOLUTIONS FOR HYDROGEN GENERATION

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Gasketed Plate
Heat Exchanger

Condenser &
Dry 
Cooler

Service

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Shell & Tube
Double Safety
Heat Exchanger

FIND OUT MORE ABOUT
HYDROGEN STORAGE & TRANSPORTATION

EPISODES

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HYDROGEN GENERATION

HYDROGEN STORAGE & TRANSPORTATION

HYDROGEN UTILIZATION

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